Fairy Tail app game Wikia
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There is only one way to attain a six star card and that is through evolving a five star card. Evolving a card requires gold coins, evolutionary stones, and one other copy of the five star card that you are evolving. The 5th time a card is evolved, it requires two copies of the card, but after this final evolution it will become a six star card.  

Additional Information[]

There are 2 other ways to attain a six star card, but this is "only" for the 6 Star Card  for advancing. You can gain it when you reach a high number at recharging diamonds or when you manage it to obtain 100 fragments from the black market. 

Names Qualification Type of Boost 5 Star Card 4 Star Card 3 Star Card 2 Star Card
Tempesta SS Magic Yes No No No
END SS All Yes No No No
Wendy SS- Magic Yes Yes Yes Yes
Makarov SS Power Yes Yes Yes No
Jellal SS All Yes Yes Yes Yes
Sayla SS All Yes No No No
Gray SS Magic Yes Yes Yes Yes
Ezel SS All Yes No No No
Erza SS Power Yes Yes Yes Yes
Mard SS Attack Yes No No No
Zeref SS+ All Yes No No No
Acnologia SS Power No No No No
Jackal SS Attack Yes No No No
Keith SS Magic Yes No No No
Dragon BOSS SS Power No No No No
Silver SS Power Yes No No No
Torafusa SS Attack Yes No No No
6 Star Card SS- All No No No No
Gildarts SS Attack Yes Yes Yes No
Natsu SS All Yes Yes Yes Yes
Laxus SS All Yes Yes Yes Yes
Mirajane SS Power Yes Yes Yes Yes
Kyouka SS Power Yes No No No
Gajeel SS Power Yes Yes Yes No
Mavis Vermilion SS+ All Yes No No No
Franmalth SS Power Yes No No No
Mystogan SS All Yes Yes Yes Yes
Hades SS All Yes No No No
Lucy SS- Magic Yes Yes Yes Yes
Bluenote SS- Attack Yes Yes No No
Zero SS- Power Yes Yes No No
Future Rogue SS Attack Yes No No No
Spirit King SS- Power Yes No No No
Minerva SS- All Yes Yes No No
Rogue SS- Attack Yes Yes Yes No
Brain SS- All Yes Yes No No
Sting SS- Attack Yes Yes Yes No
Jura SS- All Yes Yes No No
Kagura SS- Attack Yes Yes Yes Yes
C. Juvia SS Magic Yes No No No
C. Erza SS Power Yes No No No
C. Lucy SS Magic Yes No No No
Irene SS+ All Yes No No No
Meredy SS Magic Yes Yes Yes No
Cana SS- Magic Yes Yes Yes Yes
Yukino S- Magic Yes Yes Yes No
Cobra S- Attack Yes Yes Yes No
Porlyusica SS- Magic Yes Yes Yes No
Chelia SS- Magic Yes Yes Yes No
Lyon SS- Magic Yes Yes Yes Yes
Larcade SS Power Yes Yes No No
God Serena SS+ Attack Yes Yes No No
Brandish SS+ All Yes Yes No No
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